And when perfected, this approach might also cook up the solar cells in a microwave oven similar to the one in most kitchens.
These nanoparticles of copper zinc tin sulfide are processed with a common antifreeze solvent to produce good quality solar cells. (Image courtesy of Oregon State University)
Engineers at Oregon State University have determined that ethylene glycol, commonly used in antifreeze products, can be a low-cost solvent that functions well in a “continuous flow” reactor – an approach to making thin-film solar cells that is easily scaled up for mass production at industrial levels.
The research, just published in Material Letters, a professional journal, also concluded this approach will work with CZTS, or copper zinc tin sulfide, a compound of significant interest for solar cells due to its excellent optical properties and the fact these materials are cheap and environmentally benign.
“The global use of solar energy may be held back if the materials we use to produce solar cells are too expensive or require the use of toxic chemicals in production,” said Greg Herman, an associate professor in the OSU School of Chemical, Biological and Environmental Engineering. “We need technologies that use abundant, inexpensive materials, preferably ones that can be mined in the U.S. This process offers that.”
By contrast, many solar cells today are made with CIGS, or copper indium gallium diselenide. Indium is comparatively rare and costly, and mostly produced in China. Last year, the prices of indium and gallium used in CIGS solar cells were about 275 times higher than the zinc used in CZTS cells.
The technology being developed at OSU uses ethylene glycol in meso-fluidic reactors that can offer precise control of temperature, reaction time, and mass transport to yield better crystalline quality and high uniformity of the nanoparticles that comprise the solar cell – all factors which improve quality control and performance.
This approach is also faster – many companies still use “batch mode” synthesis to produce CIGS nanoparticles, a process that can ultimately take up to a full day, compared to about half an hour with a continuous flow reactor. The additional speed of such reactors will further reduce final costs.
“For large-scale industrial production, all of these factors – cost of materials, speed, quality control – can translate into money,” Herman said. “The approach we’re using should provide high-quality solar cells at a lower cost.”
The performance of CZTS cells right now is lower than that of CIGS, researchers say, but with further research on the use of dopants and additional optimization it should be possible to create solar cell efficiency that is comparable.
This project is one result of work through the Center for Sustainable Materials Chemistry, a collaborative effort of OSU and five other academic institutions, supported by the National Science Foundation. Funding was provided by Sharp Laboratories of America. The goal is to develop materials and products that are safe, affordable and avoid the use of toxic chemicals or expensive compounds.
The study this story is based on is available in ScholarsArchive@OSU; http://bit.ly/10Zj0SK
About the OSU College of Engineering: The OSU College of Engineering is among the nation¹s largest and most productive engineering programs. Since 1999, the college has more than tripled its research expenditures to $37.2 million by emphasizing highly collaborative research that solves global problems, spins out new companies, and produces opportunity for students through hands-on learning.
Greg Herman | EurekAlert!
Argon is not the 'dope' for metallic hydrogen
24.03.2017 | Carnegie Institution for Science
Researchers make flexible glass for tiny medical devices
24.03.2017 | Brigham Young University
Astronomers from Bonn and Tautenburg in Thuringia (Germany) used the 100-m radio telescope at Effelsberg to observe several galaxy clusters. At the edges of these large accumulations of dark matter, stellar systems (galaxies), hot gas, and charged particles, they found magnetic fields that are exceptionally ordered over distances of many million light years. This makes them the most extended magnetic fields in the universe known so far.
The results will be published on March 22 in the journal „Astronomy & Astrophysics“.
Galaxy clusters are the largest gravitationally bound structures in the universe. With a typical extent of about 10 million light years, i.e. 100 times the...
Researchers at the Goethe University Frankfurt, together with partners from the University of Tübingen in Germany and Queen Mary University as well as Francis Crick Institute from London (UK) have developed a novel technology to decipher the secret ubiquitin code.
Ubiquitin is a small protein that can be linked to other cellular proteins, thereby controlling and modulating their functions. The attachment occurs in many...
In the eternal search for next generation high-efficiency solar cells and LEDs, scientists at Los Alamos National Laboratory and their partners are creating...
Silicon nanosheets are thin, two-dimensional layers with exceptional optoelectronic properties very similar to those of graphene. Albeit, the nanosheets are less stable. Now researchers at the Technical University of Munich (TUM) have, for the first time ever, produced a composite material combining silicon nanosheets and a polymer that is both UV-resistant and easy to process. This brings the scientists a significant step closer to industrial applications like flexible displays and photosensors.
Silicon nanosheets are thin, two-dimensional layers with exceptional optoelectronic properties very similar to those of graphene. Albeit, the nanosheets are...
Enzymes behave differently in a test tube compared with the molecular scrum of a living cell. Chemists from the University of Basel have now been able to simulate these confined natural conditions in artificial vesicles for the first time. As reported in the academic journal Small, the results are offering better insight into the development of nanoreactors and artificial organelles.
Enzymes behave differently in a test tube compared with the molecular scrum of a living cell. Chemists from the University of Basel have now been able to...
20.03.2017 | Event News
14.03.2017 | Event News
07.03.2017 | Event News
24.03.2017 | Materials Sciences
24.03.2017 | Physics and Astronomy
24.03.2017 | Physics and Astronomy