In the August 9-13 edition of the Proceedings of the National Academy of Sciences, the team presents a new way to image and analyze the mechanical stress that causes colloidal coatings—those in which microscopic particles of one substance are dispersed throughout another—to peel off of surfaces.
Understanding how and why coatings fail has broad applications in the physical and biological sciences, said Eric Dufresne, the John J. Lee Associate Professor of Mechanical Engineering at Yale and lead author of the study.
“Coatings protect almost every surface you encounter, from paint on a wall to Teflon on a frying pan to the skin on our own bodies. When coatings peel and crack they put the underlying material at risk,” Dufresne said. “Our research is aimed at pinpointing the failure of coatings. We’ve developed this new technique to zoom in on coatings and watch them fail at the microscopic level.”
To visualize the microscopic motion of paint in 3D, the team mixed in tiny fluorescent particles that glow when illuminated by a laser. By tracing the motion of these particles over time with a microscope, they captured the motion of the paint as it peeled and dried in detail.
In addition, the team was able to track the 3-D forces generated by the paint as it dried, producing a “stress map” of the mechanical deformation of the coating as it failed. “The trick was to apply the paint to a soft surface, made of silicone rubber, that is ever so slightly deformed by the gentle forces exerted by the drying paint,” Dufresne said.
Although the current study focuses on colloidal coatings, the technique could be applied to all kinds of coatings, Dufresne said. Next, the team hopes to improve on current methods for mitigating peeling in a wide range of coatings.
“This is a completely new way of looking at a very old problem.”
Other authors of the study include Ye Xu, Wilfried Engl, Elizabeth Jerison and Callen Hyland (Yale University); Kevin Wallenstein (Princeton University); and Larry Wilen (Unilever).
Citation: DOI: 10.1073/pnas.1005537107
PRESS CONTACT: Suzanne Taylor Muzzin 203-432-8555
Suzanne Taylor Muzzin | EurekAlert!
Smart Data Transformation – Surfing the Big Wave
02.12.2016 | Fraunhofer-Institut für Angewandte Informationstechnik FIT
Climate change could outpace EPA Lake Champlain protections
18.11.2016 | University of Vermont
Have you ever wondered how you see the world? Vision is about photons of light, which are packets of energy, interacting with the atoms or molecules in what...
A multi-institutional research collaboration has created a novel approach for fabricating three-dimensional micro-optics through the shape-defined formation of porous silicon (PSi), with broad impacts in integrated optoelectronics, imaging, and photovoltaics.
Working with colleagues at Stanford and The Dow Chemical Company, researchers at the University of Illinois at Urbana-Champaign fabricated 3-D birefringent...
In experiments with magnetic atoms conducted at extremely low temperatures, scientists have demonstrated a unique phase of matter: The atoms form a new type of quantum liquid or quantum droplet state. These so called quantum droplets may preserve their form in absence of external confinement because of quantum effects. The joint team of experimental physicists from Innsbruck and theoretical physicists from Hannover report on their findings in the journal Physical Review X.
“Our Quantum droplets are in the gas phase but they still drop like a rock,” explains experimental physicist Francesca Ferlaino when talking about the...
The Max Planck Institute for Physics (MPP) is opening up a new research field. A workshop from November 21 - 22, 2016 will mark the start of activities for an innovative axion experiment. Axions are still only purely hypothetical particles. Their detection could solve two fundamental problems in particle physics: What dark matter consists of and why it has not yet been possible to directly observe a CP violation for the strong interaction.
The “MADMAX” project is the MPP’s commitment to axion research. Axions are so far only a theoretical prediction and are difficult to detect: on the one hand,...
Broadband rotational spectroscopy unravels structural reshaping of isolated molecules in the gas phase to accommodate water
In two recent publications in the Journal of Chemical Physics and in the Journal of Physical Chemistry Letters, researchers around Melanie Schnell from the Max...
16.11.2016 | Event News
01.11.2016 | Event News
14.10.2016 | Event News
05.12.2016 | Power and Electrical Engineering
05.12.2016 | Information Technology
05.12.2016 | Earth Sciences